Scientists develop self-healing battery using stretchy polymer

Stanford and SLAC researchers have developed a self-healing battery electrode that could be used in electric cars, mobile phones and other devices. The development is expected to significantly increase the life of lithium-ion batteries.

Researchers have used a stretchy polymer to coat the electrode, bind it together and spontaneously heal tiny cracks that develop during battery operation, said the team from Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory.

Their findings have been reported in Nature Chemistry.

Chao Wang, a postdoctoral researcher at Stanford and one of two principal authors of the paper, developed the self-healing polymer and added tiny nanoparticles of carbon to the polymer so it would conduct electricity.

“We found that silicon electrodes lasted 10 times longer when coated with the self-healing polymer, which repaired any cracks within just a few hours,” Bao said.

“Their capacity for storing energy is in the practical range now, but we would certainly like to push that,” said Yi Cui, an associate professor at SLAC and Stanford who led the research with Bao. The electrodes worked for about 100 charge-discharge cycles without significantly losing their energy storage capacity.

“That’s still quite a way from the goal of about 500 cycles for [mobile] phones and 3000 cycles for an electric vehicle,” Cui said, “but the promise is there, and from all our data it looks like it’s working.”

This prototype lithium-ion battery contains a silicon electrode protected with a coating of self-healing polymer. The cables and clips in the background are part of an apparatus for testing the battery’s performance. (Photo credit: Brad Plummer/SLAC)

Making a more flexible battery

Researchers worldwide are racing to find ways to store more energy in the negative electrodes of lithium-ion batteries to achieve higher performance while reducing weight. One of the most promising electrode materials is silicon; it has a high capacity for soaking up lithium ions from the battery fluid during charging and then releasing them when the battery is put to work.

But this high capacity comes at a price: silicon electrodes swell to three times their normal size and shrink back down again each time the battery charges and discharges. The brittle material soon cracks and falls apart, degrading battery performance. This is a problem for all electrodes in high-capacity batteries, said Hui Wu, a former Stanford postdoc who is now a faculty member at Tsinghua University in Beijing, and the other principal author of the paper.

To make the self-healing coating, scientists deliberately weakened some of the chemical bonds within polymers - long, chain-like molecules with many identical units. The resulting material breaks easily, but the broken ends are chemically drawn to each other and quickly link up again, mimicking the process that allows biological molecules such as DNA to assemble, rearrange and break down.

Researchers in Cui’s lab and elsewhere have tested a number of ways to keep silicon electrodes intact and improve their performance. Some are being explored for commercial uses, but many involve exotic materials and fabrication techniques that are challenging to scale up for production.

The self-healing electrode, which is made from silicon microparticles that are widely used in the semiconductor and solar cell industry, is the first solution that seems to offer a practical road forward, Cui said. The researchers said they think this approach could work for other electrode materials as well, and they will continue to refine the technique to improve the silicon electrode’s performance and longevity.

The research team also included Zheng Chen and Matthew T McDowell of Stanford. Cui and Bao are members of the Stanford Institute for Materials and Energy Sciences, a joint SLAC/Stanford institute. The research was funded by the Department of Energy through SLAC’s Laboratory Directed Research and Development program and by the Precourt Institute for Energy at Stanford.