Bent nanowires could be less likely to fail
Arranging silver nanowires in bent configurations may make them more durable and less likely to fail inside electronic devices, according to researchers from King Abdullah University of Science and Technology (KAUST). These nanowires form flexible, transparent conductive layers that can be used for improved solar cells, strain sensors and next-generation mobile phones.
Applying nanotechnology in electronic devices requires rigorous testing of individual tiny components to ensure they will stand up to use. Silver nanowires show great promise as connectors that could be arranged in flexible, near-transparent meshes for touch screens or solar cells, but it is unclear how they will respond to prolonged stresses from bending and carrying current.
Testing the bulk properties of a large sample of nanoparticles is easy, but not completely revelatory. However, adopting transmission electron microscopy (TEM) makes it possible to examine individual nanoparticles. KAUST PhD student Nitin Batra and his supervisor Pedro Da Costa are at the forefront of developing new TEM techniques, which has allowed them to study single silver nanowires in detail.
“A major part of our work has been designing and fabricating sample platform prototypes (or chips) for TEM, which allow us to characterise and manipulate nanomaterials with an unsurpassed spatial resolution,” Batra said. Now, to improve on expensive commercially available chips that contain a very fragile membrane to support nanoparticles, the researchers have submitted to patent their own robust, re-usable chips that don’t require a membrane.
The researchers suspended silver nanowires from platinum electrodes over their custom-made TEM chips and applied a range of voltages until the nanowires failed due to heating by the electrical current. They found that straight nanowires tended to snap when they reached a certain high current density, at points determined by local structural defects.
More interesting behaviour was seen when the nanowires were bent from the beginning. These samples tended to buckle instead of snapping at high voltage and exhibited an ability to self-heal because they remained held together by the carbon coating on the outside of the wires. Some nanowires even exhibited resonant vibrations, like the harmonics on a guitar string, before they failed.
“Many devices are expected to undergo repeated bending and twisting by the end user, which means that it is not realistic to limit the study of the electrical response of silver nanowires to straight configurations,” Batra said. “Our results suggest that the failure rate of such devices could be minimised by using bent nanowires instead of straight ones. The self-healing capability could effectively delay the breakdown of the circuit.”
The research has been published in the journal Nanoscale.
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