Improving absorber layers in perovskite solar cells
A synthetic approach that improves absorber layers in perovskite solar cells could help them achieve their full potential and draw closer to the performance of leading gallium arsenide devices, according to researchers from the King Abdullah University of Science and Technology (KAUST).
Solar cells that rely on perovskite thin films to capture sunlight are the fastest growing photovoltaic technology. Cheaper and easier to manufacture and incorporate into devices than conventional semiconductors, lead halide perovskites also effectively absorb visible light and display long charge carrier diffusion lengths — an indicator of their ability to maintain light-induced electrons and holes separation and facilitate charge transport.
Performance of solar cells hinges on absorber materials with a high-quality crystal structure and a narrow bandgap to maximise sunlight harvesting. This optimal bandgap range spans energies of 1.1 to 1.4 eV, which corresponds to near-infrared wavelengths. But while absorber layers containing polycrystalline lead halide perovskites have provided high-efficiency solar cells, their performance has been affected by considerable structural disorder and defects.
Formamidinium lead triiodide features the smallest bandgap to date, but this bandgap exceeds the optimal range for single-junction devices. One way to reduce the bandgap of perovskites involves forming lead–tin alloys in the absorber, but this introduces crystal defects and instability. Now KAUST researchers have developed an approach using a microns-thick absorber layer consisting of perovskite single crystals to minimise the bandgap; the crystals contain a mixture of methylammonium and formamidinium organic cations.
The researchers incorporated the mixed-cation perovskite into unconventional inverted p–i–n solar cells, in which the absorber is sandwiched between an electron transport top layer and a hole transport bottom layer. The resulting solar cells exhibited an efficiency of 22.8%, surpassing the best-performing devices using single-crystal methylammonium lead triiodide. The results were published in the journal Energy & Environmental Science.
“We had known that mixed-cation single-crystal absorbers could outperform single-cation absorbers due to their lower bandgap and superior optoelectronic qualities; however, this had not been realised before because of challenges in crystal growth and device integration,” said KAUST PhD student Abdullah Alsalloum.
The external quantum efficiency of the mixed-cation perovskite film, which measures its effectiveness when converting incoming light into charge carriers, shifted toward near-infrared wavelengths from that of polycrystalline formamidinium lead triiodide, consistent with its smaller bandgap. “By utilising a thicker single-crystal absorber layer, we expanded the absorption range of the film so that it’s very close to the optimal range,” Alsalloum said.
The team is now working on enhancing device performance and stability to get even closer to the top-performing gallium arsenide solar cells. According to Alsalloum, “Future studies include optimising device interfaces and exploring more favourable device structures.”
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