Many industries are calling for electronics that can operate reliably in a harsh environment, including extreme temperatures above 200°C. Examples of the high-temperature applications include turbine engine control in aerospace and electronics or sensors used for drilling operation in oil and gas industry. Although traditional cooling systems can help electronics function at high temperatures, in some applications, cooling may not be possible - or it may be more appealing for the electronics to operate hot to improve system reliability or reduce cost. However, the availability of transistors and circuits for high-temperature operation is very limited.
Now a team of researchers from the University of California, Riverside and Rensselaer Polytechnic Institute have discovered that molybdenum disulfide (MoS2), a semiconductor material, may be a promising candidate to make thin-film transistors for extreme temperature applications. “Our study shows that molybdenum disulfide thin-film transistors remain functional to high temperatures of at least 500 K [220°C],” said Alexander Balandin, the team leader and a professor at the Department of Electrical and Computer Engineering at the UC-Riverside. The findings have been published in the Journal of Applied Physics, from AIP Publishing.
“The transistors also demonstrate stable operation after two months of ageing, which suggests new applications for molybdenum disulfide thin-film transistors in extreme-temperature electronics and sensors.”
Molybdenite, a mineral of molybdenum disulfide, is an abundant, naturally occurring material, which is commonly used as an additive in lubricants. Molybdenum disulfide synthesised by chemical vapour deposition has been found to be a promising material for manufacturing flexible, thin-film transistors - devices that control the movement of electrons and electric current, like a water faucet. According to Balandin, molybdenum disulfide belongs to a family called van der Waals materials, which have characteristic layered crystal structure with atomic layers weakly bonded to each other. The weak connection between atomic sheets enables exfoliation of such materials layer by layer, similar to the process used for obtaining graphene by peeling thin sheets off chunks of graphite. The layered structure also suggests that extremely thin and high-quality layers can also be produced by chemical vapour deposition on an industrial scale.
“Although devices made of conventional large-band-gap semiconductors, such as silicon carbide or gallium nitride, hold promise for extended high-temperature operation, they are still not cost effective for high-volume applications,” Balandin said. “A single-layer molybdenum disulfide shows a band gap of 1.9 eV, which is larger than that of silicon and gallium arsenide. This is beneficial for the proposed application.” The presence of a larger band gap means that a device can be easily switched on and off, a crucial property for a transistor’s operation.
Using standard lithography techniques in a cleanroom environment, Balandin’s team built molybdenum disulfide transistors on silicon substrates for high-temperature experiments. Some had just a few layers (1-3) and others had more, multiple layers (15-18). The relatively thick films were more thermally stable and demonstrated a higher mobility at elevated temperatures, according to Balandin.
By conducting direct current measurement, a technique applying constant voltage or current through the device for a relatively long time, researchers studied the current-voltage characteristics or functional performance of the fabricated transistor at temperatures from 300 to 500 K. They found that the device performed differently but remained functional as the temperature increased.
“Both mobility and threshold voltage decrease with temperature,” Balandin said. “Decreasing mobility results in current decrease through the device channel, while decreasing threshold voltage leads to current increase. Therefore, the exact behaviour of current with increasing temperature would depend on the interplay of decreasing mobility and threshold voltage.”
Another intriguing feature researchers observed is a characteristic ‘kink’ on the current-voltage graph at the zero voltage for temperatures higher than 450 K. This ‘memory effect’ is similar to one observed in graphene transistors and electron glasses and suggests the material’s potential for use in high-temperature sensors.
According to Balandin, practical application of molybdenum disulfide transistors in control circuits or sensors at high temperatures requires operation longer than one month. After two months, the team found the aged devices demonstrated a stable operation and were characterised by a higher threshold voltage, lower mobility and weaker temperature dependence of the mobility.
The researchers’ next step is to study the high-temperature function of molybdenum disulfide transistors and circuits, fabricated by industrial methods such as chemical vapour deposition.
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